Sine-Gordon theory for the equation of state of classical hard-core Coulomb systems. II. High-temperature expansion

We perform a high-temperature expansion of the grand potential of the restrictive primitive model of electrolytes in the frame of the extended sine-Gordon theory exposed in the companion paper. We recover a result already obtained by Stell an Lebowitz (J. Chem. Phys., 49, 3706 (1968)) by means of diagrammatic expansions

Integrating and validating urban simulation models

Urban systems are intrinsically complex, involving different dimensions and scales, and consequently various approaches and scientific disciplines. In that context, urban simulation models have been coined as essential for the construction of evidence-based and integrated urban sciences. This review and position paper synthesises previous work focused on coupling and integrating urban models on the one hand, and exploring and validating such simulation models on the other hand. These research directions are complementary basis for a research program towards the development of integrated urban theories, with some application perspectives to sustainable territorial planning

Estimating public transport congestion in UK urban areas with open transport models

Operational urban transport models require to gather heterogeneous sets of data and often integrate different sub-models. Their systematic validation and reproducible application therefore remains problematic. We propose in this contribution to build transport models from the bottom-up using scientific workflow systems with open-source components and data. These open models are aimed in particular at estimating congestion of public transport in all UK urban areas. This allows us building health indicators related to public transport density in the context of the COVID-19 crisis, and testing related policies

A scala library for spatial sensitivity analysis

The sensitivity analysis and validation of simulation models require specific approaches in the case of spatial models. We describe the spatialdata scala library providing such tools, including synthetic generators for urban configurations at different scales, spatial networks, and spatial point processes. These can be used to parametrize geosimulation models on synthetic configurations, and evaluate the sensitivity of model outcomes to spatial configuration. The library also includes methods to perturb real data, and spatial statistics indicators, urban form indicators, and network indicators. It is embedded into the OpenMOLE platform for model exploration, fostering the application of such methods without technical constraints

Empowering urban governance through urban science: Multi-scale dynamics of urban systems worldwide

Cities are facing many sustainability issues in the context of the current global interdependency characterized by an economic uncertainty coupled to climate changes, which challenge their local policies aiming to better conciliate reasonable growth with livable urban environment. The urban dynamic models developed by the so-called “urban science” can provide a useful foundation for more sustainable urban policies. It implies that their proposals have been validated by correct observations of the diversity of situations in the world. However, international comparisons of the evolution of cities often produce unclear results because national territorial frameworks are not always in strict correspondence with the dynamics of urban systems. We propose to provide various compositions of systems of cities in order to better take into account the dynamic networking of cities that go beyond regional and national territorial boundaries. Different models conceived for explaining city size and urban growth distributions enable the establishing of a correspondence between urban trajectories when observed at the level of cities and systems of cities. We test the validity and representativeness of several dynamic models of complex urban systems and their variations across regions of the world, at the macroscopic scale of systems of cities. The originality of the approach resides in the way it considers spatial interaction and evolutionary path dependence as major features in the general behavior of urban entities. The models studied include diverse and complementary processes, such as economic exchanges, diffusion of innovations, and physical network flows. Complex systems dynamics is in principle unpredictable, but contextualizing it regarding demographic, income, and resource components may help in minimizing the forecasting errors. We use, among others, a new unique source correlating population and built-up footprint at world scale: the Global Human Settlement built-up areas (GHS-BU). Following the methodology and results already obtained in the European GeoDiverCity project, including USA, Europe, and BRICS countries, we complete them with this new dataset at world scale and different models. This research helps in further empirical testing of the hypotheses of the evolutionary theory of urban systems and partially revising them. We also suggest research directions towards the coupling of these models into a multi-scale model of urban growth

Nitrous oxide distribution and its origin in the central and eastern South Pacific Subtropical Gyre

The mechanisms of microbial nitrous oxide (N<sub>2</sub>O) production in the ocean have been the subject of many discussions in recent years. New isotopomeric tools can further refine our knowledge of N<sub>2</sub>O sources in natural environments. This study compares hydrographic, N<sub>2</sub>O concentration, and N<sub>2</sub>O isotopic and isotopomeric data from three stations along a coast-perpendicular transect in the South Pacific Ocean, extending from the center (Sts. GYR and EGY) of the subtropical oligotrophic gyre (~26° S; 114° W) to the upwelling zone (St. UPX) off the central Chilean coast (~34° S). Although AOU/N<sub>2</sub>O and NO<sub>3</sub><sup>−</sup> trends support the idea that most of the N<sub>2</sub>O (mainly from intermediate water (200–600 m)) comes from nitrification, N<sub>2</sub>O isotopomeric composition (intramolecular distribution of <sup>15</sup>N isotopes) expressed as SP (site preference of <sup>15</sup>N) shows low values (10 to 12permil) that could be attributed to the production through of microbial nitrifier denitrification (reduction of nitrite to N<sub>2</sub>O mediated by ammonium oxidizers). The coincidence of this SP signal with high – stability layer, where sinking organic particles can accumulate, suggests that N<sub>2</sub>O could be produced by nitrifier denitrification inside particles. It is postulated that deceleration of particles in the pycnocline can modify the advection - diffusion balance inside particles, allowing the accumulation of nitrite and O<sub>2</sub> depletion suitable for nitrifier denitrication. As lateral advection seems to be relatively insignificant in the gyre, in situ nitrifier denitrification could account for 40–50% of the N<sub>2</sub>O produced in this layer. In contrast, coastal upwelling system is characterized by O<sub>2</sub> deficient condition and some N deficit in a eutrophic system. Here, N<sub>2</sub>O accumulates up to 480% saturation, and isotopic and isotopomer signals show highly complex N<sub>2</sub>O production processes, which presumably reflect both the effect of nitrification and denitrification at low O<sub>2</sub> levels on N<sub>2</sub>O production, but net N<sub>2</sub>O consumption by denitrification was not observed